In situ characterization of dolomite crystals: Evaluation of dolomitization process and its effect on zoning          下载免费PDF全文

Babatunde John Olanipekun  Karem Azmy 《Sedimentology》2017,64(6):1708-1730

Dolomitization is a dissolution–re‐precipitation process which proceeds via micrometre‐scale interface reaction horizons. However, the effect of this fundamental local medium of replacement process on precipitated dolomite crystals is rarely investigated. For this purpose, dolomite samples of Ordovician Boat Harbour Formation carbonates (Newfoundland, Canada) from Main Brook and Daniel's Harbour (about 150 km apart) were studied. The investigation used high‐resolution approaches to carry out imaging and elemental analyses of individual dolomite crystals, including scanning electron microscopy, scanning electron microscopy‐based cathodoluminescence, secondary ion mass spectrometry and electron microprobe analysis. The purpose was to better understand geochemical variations across the crystal traverses and their association with dolomite replacement processes and conditions. The scanning electron microscopy‐based cathodoluminescence‐zoning character reveals three major crystal facies. Distinctly (planar boundaries) zoned core and indistinctly zoned core are zoned dolomite crystal facies in burial dolomite from Main Brook. Relatively unzoned crystal facies was identified in that of Daniel's Harbour. Compositionally zoned dolomite crystals are characterized by decreasing Sr, Na, Y and ∑REE but increasing Mn and Fe from core to rim sections. ‘Core to rim’ zoning was not found for major (Mg and Ca) elements. The zoning exhibited by the replacive dolomite crystals is interpreted to be, principally, a result of limited exchange between solutes of the bulk pore fluid and those of dissolving precursor marine carbonate. In tandem with petrographic features, the systematic compositional zoning character demonstrates that the effectiveness of the dolomitization process grades from indistinctly zoned core to relatively unzoned crystal facies via interface reaction horizons. Homogenization of major elements of core and rim sections, seen in distinctly zoned core crystal facies and to a much greater extent in relatively unzoned crystal facies, via a secondary reaction interface, is the first recognized stage of the ‘maturation process’ followed by homogenization of the trace elements seen largely in relatively unzoned crystal facies.  相似文献   

Mineralogical,petrographic and fluid inclusion evidence for the link between boiling and epithermal Ag-Au mineralization in the La Luz area,Guanajuato Mining District,México     

《Ore Geology Reviews》2017

Theoretical, experimental and observation data provide strong evidence that boiling is the dominant depositional mechanism in many low to intermediate sulfidation epithermal precious metals deposits. Textural and petrographic features that are evidence for boiling in the epithermal environment include the presence of coexisting liquid-rich and vapor-rich fluid inclusions, assemblages consisting of only vapor-rich fluid inclusions, colloform quartz, adularia and bladed calcite. We have examined 213 samples collected from surface outcrops, underground workings and drill cores from the central part of the La Luz vein system in the Guanajuato mining district, Mexico. In each sample, the various features that are evidence of boiling have been recorded. These observations have been quantified using a Boiling Confidence Factor that provides a means of scoring and rating each sample or area relative to the likelihood that boiling occurred.Homogenization temperatures of liquid-rich fluid inclusions within assemblages of coexisting liquid-rich and vapor-rich fluid inclusions have been measured to estimate the depth of trapping of the inclusions, and these data have been used to estimate the depth to the 300 °C isotherm along the La Luz vein system.Fluid inclusions and mineral textural features show strong evidence of boiling in the deepest levels sampled in the La Luz system. This observation suggests that the bottom of the boiling zone is at some depth beneath the deepest levels explored and opens the potential for additional resources at depth.  相似文献   

巯基棉分离富集ICP-OES测定岩盐矿中的水溶性铜铅锌镉     

刘芳  黄瑞成  戴伟峰  魏灵巧  罗磊  李灵凤 《岩矿测试》2017,36(3):252-257

盐岩矿的水溶法开采是获得人类生活必需品和重要工业原料——盐的重要途径之一。在水溶法开采中,岩盐矿中的水溶性重金属会随着母液到达地表环境和后续的岩盐产品中,可能对地表环境造成污染和危害人体健康,故对岩盐矿中水溶性重金属的检测非常重要。岩盐矿中的水溶性铜铅锌镉含量较低,而盐分含量过高,过高的盐分含量会影响ICP-OES的雾化效率,故很难用ICP-OES直接测量重金属含量。本文以巯基棉为吸附材料,从溶液pH、洗脱液浓度、洗脱液体积等方面研究了分离富集岩盐矿中水溶性铜铅锌镉的实验条件。结果表明,在pH=7的介质中,巯基棉对铜铅锌镉有良好的吸附性能,被吸附的铜铅锌镉可用7 m L盐酸(15%)定量洗脱,溶液中的钠对吸附无明显影响。对解吸后的溶液,铜铅锌镉的回收率均≥92.2%,钠回收率仅0.04%,基本实现了铜铅锌镉与钠的分离,达到了ICP-OES检测要求。  相似文献   

疏水性螯合物固相萃取-原子吸收光谱法测定海水中5种重金属   总被引：1，自引：1，他引：0  

王增焕  王许诺  谷阳光  陈瑛娜 《岩矿测试》2017,36(4):360-366

海水重金属的含量变化与分布特征受海洋中生物地球化学过程控制。海水重金属测定的难点在于海水盐度高且重金属含量低,需要进行分离、富集等样品前处理。常规前处理方法如溶剂萃取样品量大、操作繁琐,使用大量有机溶剂,对环境和操作者危害大;共沉淀法容易造成污染。本研究以吡咯烷基二硫代甲酸铵和二乙氨基二硫代甲酸钠为螯合剂,采用商品化的固相萃取柱,分离海水中的镉、铜、铅、镍和锌5种重金属,原子吸收光谱法测定其含量。结果表明:5种元素工作曲线的相关性较好(R0.999),镉锌的线性范围分别为0~4!g/L和0~100!g/L,铅铜镍的线性范围为0~40!g/L;检出限(!g/L)分别为0.02、2.6、0.06、0.18、0.3,方法精密度高(RSD5%),加标回收率为93.8%~104%。本方法利用疏水性作用的固相萃取技术,实现了海水分析的绿色样品前处理。  相似文献   

Risk assessment of heavy metals in topsoil along the banks of theYangtze River in Huangshi,China          下载免费PDF全文

LIN Dan  JIN Meng-gui  LI Xiu-juan 《地下水科学与工程》2017,5(2):162-172

High concentrations of heavy metal in farmland threatens food production and human health. Our study assesses soil quality and the distribution of Cd, Cr, Cu, Zn, Pb and Ni, to identify possible sources of heavy metals along the banks of the Yangtze River in Huangshi. Heavy metal concentrations of 22 topsoil samples were measured using the inductively coupled plasma mass spectrometry instrument and data was analyzed by multivariate statistic approaches. Heavy metal contamination risk assessment was performed using a combination of the Nemerow multi-factor index method, the Hakanson potential ecological risk index method and the Muller index of geo-accumulation method. These methods determined similar results indicating that cadmium (Cd) poses a health risk to residents at the study site while Cr, Cu, Zn, Pb and Ni do not. The Nemerow multi-factor index method demonstrated that 18 samples were heavily polluted, three moderately polluted and one lightly polluted. The Muller index of geo-accumulation method found ten samples were moderately to strongly polluted by Cd, five were moderately polluted, six were lightly to moderately polluted and one was lightly polluted. The Hakanson potential ecological risk index method proved six samples were strongly polluted, seven were moderately polluted and nine were lightly polluted. Since our sampling sites were all in agricultural lands, we recommend the potential ecological risk index method as the most effective given it not only considers the range of pollutants contributing to soil pollution but factors in heavy metals toxicity. We are apt that the source of the high concentrations of Cd found in topsoil is derived from alluvial sediments upstream of the Yangtze River with a high percentage of residual speciation and a low percentage of exchangeable speciation distribution of Cd. This in turns indicates that a high concentration of Cd in soil had little impact on the natural environment. However, 31.9% of the iron-manganese oxides bound speciation indicating that such levels of Cd in soil would be potentially hazardous to the crops, particularly if exposed to a reductive condition.  相似文献   

城巴断块明月剖面陡山沱晚期沉积环境的地球化学特征     

吴富强  姚华舟 《江苏地质》2017,41(4):529-534

由于造山带地层系统混乱,部分地区甚至无法恢复、鉴别,给古环境、岩石成因及其成矿性研究带来了困难。以震旦系陡山沱组出露较完整的明月剖面为重点研究对象,通过野外观测和室内综合研究,尝试从稀土元素的配分模式、Eu/Eu*、Ce异常（Ce/Ce*和Ce/Ce**）、微量元素Sr/Ba、Sr-Mn等地球化学特征研究该地区沉积环境以及岩石成因,厘定明月剖面陡山沱晚期沉积环境为大陆边缘沉积环境,指出热水沉积作用对硅质岩成因及成矿性的影响,为下一步找矿提供思路。  相似文献   

21世纪遗迹学热点与前沿:第14届国际遗迹组构专题研讨会综述^*   总被引：1，自引：1，他引：0       下载免费PDF全文

范若颖  龚一鸣 《古地理学报》2017,19(5):919-926

第14届国际遗迹组构专题研讨会于2017年4月29日至5月2日在中国台北台湾大学顺利召开。从会议口头报告、展板、会间和会后野外地质考察以及交流讨论可以看出遗迹学热点与前沿: (1)遗迹化石的系统分类将一直是遗迹学家努力的方向,旨在为古生物学研究提供丰富的行为学资料,并为沉积学、古生态学等研究提供科学、客观和简便的遗迹分类学框架;(2)遗迹组构分析在沉积学中的深入应用,能提供大量传统沉积学、地球化学分析所无法揭示的生物学信息;(3)重大地质事件的遗迹学响应以及遗迹化石的演化古生态学为地质—生命突变期研究提供了独一无二的新素材;(4)地微生物学与遗迹学的结合进行了初步有益尝试;(5)特殊化石行为如求偶行为的报道扩大了深时行为类型;(6)定量形态表征和统计分析是遗迹学研究精细化和定量化的重要途径,通过遗迹组构分析来定量刻画沉积环境因子是遗迹组构研究的重要前景方向。  相似文献   

中国主要铂族金属供需预测及对策建议   总被引：1，自引：0，他引：1  

李鹏远  周平  齐亚彬  唐金荣  张寿庭 《地质通报》2017,36(4):676-683

铂族金属作为重要的战略性矿产,广泛应用于汽车尾气催化剂、首饰、化工催化剂、电气电子等多个领域。分析了中国铂族金属的供需现状,并运用部门消费法对中国2030年之前的铂、钯和铑3种主要金属的需求总量进行长尺度的预测,同时定量分析了未来中国铂族矿山的供应能力,认为随着国民收入的增加,对首饰及汽车的需求仍会增长,再加上汽车尾气排放标准的严格,2030年之前中国主要铂族金属的需求仍会增长,但受铂族资源禀赋限制,供应依旧乏力。针对这些问题,提出了相关对策建议。  相似文献   

唐山滨海湿地沉积物重金属污染评价     

郝彪  高莲凤  张振国  周巍  李璞壮 《城市地质》2019,14(1):48-53

通过对唐山滨海湿地表层沉积物采样,采用3种不同的方法,评价了不同采样点重金属元素Pb、Cr、Zn、Cu、Cd、As、Hg污染水平,并进行级别的划分;分析了不同重金属元素富集的影响因素,为判别其沉积物来源提供依据;通过潜在生态危害评价方法评价重金属对该区域生物的影响,以期为渤海湾重金属防治提供参考资料。结果表明,渤海湾唐山滨海湿地表层沉积物中各重金属的污染程度从大到小依次为:Pb> Cr> Zn> Cu> Cd> As> Hg;主要污染指示为Zn、Cr和Pb等元素;其表层沉积物As、Cd、Hg、Pb、Cu、Cr、Zn存在低等潜在危害程度;重金属元素对生态城生物为负面效应且偶尔发生,其中As元素的潜在危害最强。  相似文献   

A New Interlaboratory Characterisation of Silicon,Rare Earth Elements and Twenty‐Two Other Trace Element Concentrations in the Natural River Water Certified Reference Material SLRS‐6 (NRC‐CNRC)     

Delphine Yeghicheyan  Dominique Aubert  Martine Bouhnik‐Le Coz  Jrme Chmeleff  Sophie Delpoux  Irina Djouraev  Guy Granier  Franois Lacan  Jean‐Luc Piro  Tristan Rousseau  Christophe Cloquet  Aurlie Marquet  Christophe Menniti  Catherine Pradoux  Rmi Freydier  Emmanoel Vieira da Silva‐Filho  Krzysztof Suchorski 《Geostandards and Geoanalytical Research》2019,43(3):475-496

The natural river water reference material SLRS‐6 (NRC‐CNRC) is the newest batch of a quality control material routinely used in many international environmental laboratories. This work presents a nine‐laboratory compilation of measurements of major and trace element concentrations and their related uncertainties, unavailable in the NRC‐CNRC certificate (B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Y, Zr and REEs). Measurements were mostly made using inductively coupled plasma‐mass spectrometry. The results are compared with equivalent data for the last batch of the material, SLRS‐5, measured simultaneously with SLRS‐6 in this study. In general, very low concentrations, close to the quantification limits, were found in the new batch. The Sr isotopic ratio is also reported.  相似文献